部分 緒論 、物理化學(xué)實(shí)驗(yàn)的目的和要求 二、物理化學(xué)實(shí)驗(yàn)的安全知識(shí) 三、物理化學(xué)實(shí)驗(yàn)的設(shè)計(jì)思想和方法 四、誤差理論和有效數(shù)字 五、實(shí)驗(yàn)數(shù)據(jù)的表示法 art One Introduction Objective and requirement Physical chemistry laboratory safety Rules and methods for designing of the physical chemistry experiment Error theory and significant figures Data reporting 第二部分 實(shí)驗(yàn) art Two Experiments 實(shí)驗(yàn)一 燃燒熱的測(cè)定 Experiment 1 Determination of Heats of Combustion 實(shí)驗(yàn)二 溶解熱曲線的測(cè)定 Experiment 2 Determination of Heats of Solution Curve 實(shí)驗(yàn)三 凝固點(diǎn)降低法測(cè)定摩爾質(zhì)量 Experiment 3 Determination of Molar Mass by Freezing Point Depression 實(shí)驗(yàn)四 凝固點(diǎn)降低法測(cè)定氫化納注射液的滲透壓 Experiment 4 Determination of Osmotic Pressure of Sodium Chloride Injection by Freezing Point Depression 實(shí)驗(yàn)五 靜態(tài)法測(cè)定液體飽和蒸氣壓 Experiment 5 Saturated Vapor Pressure of Pure Liquids by Static Method 實(shí)驗(yàn)六 反應(yīng)平衡常數(shù)及分配系數(shù)的測(cè)定 Experiment 6 Determination of Equilibrium Constant of Reaction and Partition Coefficient 實(shí)驗(yàn)七 二組分部分§溶雙液系統(tǒng)目國(guó)的繪制 Experiment 7 Drawing of Phase Diagram for a Partially Miscible Binary Liquid System 實(shí)驗(yàn)八 §溶雙液系統(tǒng)平衡目國(guó)的繪制 Experiment 8 Drawing of Phase Diagram for a Miscible Binary Liquid System 實(shí)驗(yàn)九 二組分簡(jiǎn)單低共熔系統(tǒng)目國(guó)的繪制 Experiment 9 Drawing of Phase Diagram for a Binary utectic System 76 實(shí)驗(yàn)十 三組分液-液系統(tǒng)目國(guó)的繪制 78 Experiment 10 Drawing of Phase Diagram for a Ternary Liquid System 實(shí)驗(yàn)十一 電解質(zhì)水溶液電導(dǎo)的測(cè)定及應(yīng)用 Experiment 11 Measurement and Application of lectrolyte Solution Conductance 實(shí)驗(yàn)十二 電動(dòng)勢(shì)法測(cè)溶液 pH 相反應(yīng)熱力學(xué)函數(shù) xperiment 12 Determination of pH of Solutions and Thermodynamic Functions by lectromotive Force Measurements 實(shí)驗(yàn)十三 旋光法測(cè)定康糖轉(zhuǎn)化反應(yīng)的速率常數(shù) Experiment 13 Determination of Rate Constant for the Conversion of Sucrose by Polarimetric Method 實(shí)驗(yàn)十四 乙酸乙醋皂化反應(yīng)速率常數(shù)及活化能的測(cè)定 Experiment 14 Determination of Rate Constant and Activation nergy for the Saponification of thyl Acetate by Conductometric Method 實(shí)驗(yàn)十五 腆化擁與過(guò)氧化氫反應(yīng)的速率常數(shù)及活化能的測(cè)定 Experiment 15 Determination of Rate Constant and Activation nergy for Reaction between Potassium Iodide and Hydrogen Peroxide 實(shí)驗(yàn)十六 丙酣漠化反應(yīng)速率常數(shù)的測(cè)定 Experiment 16 Determination of Rate Constant for the Bromination of Acetone 實(shí)驗(yàn)十七 氣泡壓力法測(cè)定液體表面張力 Experiment 17 Determination of the Solution Surface Tension by Bubble Pressure Method 實(shí)驗(yàn)十八 固體在溶液中的眼附 Experiment 18 Adsorption of Solids in Solution 實(shí)驗(yàn)十九 溶膠的制備及性質(zhì) Experiment 19 Preparation and Properties of Sols 實(shí)驗(yàn)二十 黠度法測(cè)定大分子的平均目對(duì)分子質(zhì)量 Experiment 20 Determination of Average Relative Molar Mass of the Macromolecule by Viscosity Method 實(shí)驗(yàn)二十一 藥物多晶型的差熱分析(設(shè)計(jì)性實(shí)驗(yàn)) Experiment 21 Thermal Analysis of Polymorphism Pharmaceuticals(Designing xperiment) 實(shí)驗(yàn)二十二 藥物穩(wěn)定性及有效期測(cè)定(設(shè)計(jì)性實(shí)驗(yàn)) Experiment 22 Determination of Drug Stability and Shelf Life(Designing experiment) 實(shí)驗(yàn)二十三 載藥納米粒子的制備及表征(綜合設(shè)計(jì)性實(shí)驗(yàn)) Experiment 23 Preparation and Characterization of Drug-loaded Nanoparticles(Comprehensive Designing xperiment) 實(shí)驗(yàn)二十四 固體藥物常規(guī)理化常數(shù)的測(cè)定(綜合設(shè)計(jì)性實(shí)驗(yàn)) Sxperiment 24 Determination of Physical and Chemical Constants of Solid Drugs(Comprehensive Designing xperiment) 實(shí)驗(yàn)二十五 表面活性劑臨界膠束濃度的測(cè)定(綜合設(shè)計(jì)性試驗(yàn)) Experiment 25 Determination of Critical Micelle Concentration for Surfactants(Comprehensive Designing xperiment) 實(shí)驗(yàn)二十六 乳狀液的制備和性質(zhì)(綜合設(shè)計(jì)性實(shí)驗(yàn)) Experiment 26 Preparation and Properties of mulsion(Comprehensive Designing xperiment) 第三部分 實(shí)驗(yàn)測(cè)試題 一、單選題 二、司口題 三、答案 art Three Experiment Test Questions Section One Multiple Choice Section Two Short Questions Section Three Answers 第四部分 附錄 Part Four Appendices 一、 常用物理化學(xué)實(shí)驗(yàn)數(shù)據(jù)表(Common Data of xperimental Physical Chemistry) 二、 參考文獻(xiàn)(References)